2004
Vibrational relaxation of the H2O bending mode in liquid water
Publication
Publication
J. Chem. Phys. , Volume 121 p. 12143- 12145
We have studied the vibrational relaxation of the H2O bending mode in an H2O:HDO:D2O isotopic mixture using infrared pump-probe spectroscopy. The transient spectrum and its delay dependence reveal an anharmonic shift of 55±10 cm-1 for the H2O bending mode, and a value of 400±30 fs for its vibrational lifetime.
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doi.org/10.1063/1.1839175 | |
J. Chem. Phys. | |
Larsen, O. F. A., & Woutersen, S. (2004). Vibrational relaxation of the H2O bending mode in liquid water. J. Chem. Phys., 121, 12143–12145. doi:10.1063/1.1839175 |